761 research outputs found
Structural Covariance in the Hard Sphere Fluid
We study the joint variability of structural information in a hard sphere
fluid biased to avoid crystallisation and form fivefold symmetric geometric
motifs. We show that the structural covariance matrix approach, originally
proposed for on-lattice liquids [Ronceray and Harrowell, JCP 2016], can be
meaningfully employed to understand structural relationships between different
motifs and can predict, within the linear-response regime, structural changes
related to motifs distinct from that used to bias the system
Local structure of Liquid-Vapour Interfaces
The structure of a simple liquid may be characterised in terms of ground
state clusters of small numbers of atoms of that same liquid. Here we use this
sensitive structural probe to consider the effect of a liquid-vapour interface
upon the liquid structure. At higher temperatures (above around half the
critical temperature) we find that the predominant effect of the interface is
to reduce the local density, which significantly suppresses the local cluster
populations. At lower temperatures, however, pronounced interfacial layering is
found. This appears to be connected with significant orientational ordering of
clusters based on 3- and 5-membered rings, with the rings aligning
perpendicular and parallel to the interface respectively. At all temperatures,
we find that the population of five-fold symmetric structures is suppressed,
rather than enhanced, close to the interface.Comment: 10 pages, 8 figures, accepted for publication by Molecular Physic
Using mutual information to measure order in model glass-formers
Whether or not there is growing static order accompanying the dynamical
heterogeneity and increasing relaxation times seen in glassy systems is a
matter of dispute. An obstacle to resolving this issue is that the order is
expected to be amorphous and so not amenable to simple order parameters. We use
mutual information to provide a general measurement of order that is sensitive
to multi-particle correlations. We apply this to two glass-forming systems (2D
binary mixtures of hard disks with different size ratios to give varying
amounts of hexatic order) and show that there is little growth of amorphous
order in the system without crystalline order. In both cases we measure the
dynamical length with a four-point correlation function and find that it
increases significantly faster than the static lengths in the system as density
is increased. We further show that we can recover the known scaling of the
dynamic correlation length in a kinetically constrained model, the 2-TLG.Comment: 10 pages, 12 Figure
Tackling malaria, village by village: a report on a concerted information intervention by medical students and the community in Mifumi, Eastern Uganda
Background: Can an information intervention facilitated by information technology and carried out by an interdisciplinaryteam comprising medical students, technical experts, and the community itself make a positive contribution in reducing theburden of malaria at the village level? In Mifumi village in Eastern Uganda, MIFUMI Project, Makerere University College of Health Sciences Community Based Education and Service program (COBES), and the U.S. National Library of Medicine carried out a series of activities between 2007 and 2010.Methods: The team surveyed the community’s knowledge of malaria prevention and treatment; implemented a healthinformation intervention using tutorials in a variety of media; and observed the community’s use of previously distributedinsecticide treated nets (ITNs) using a digital pen application.Results: As a result of concerted education and outreach, the village residents have a good understanding of malaria preventionand treatment seeking behaviors. Leveraging the power of information technology and interdisciplinary teamwork,medical students and the denizens of a rural community were able to engage in an interactive experience of health educationand promotion.Conclusion: Preliminary observations suggest that a health information intervention in concert with a collaborative communityeffort of education and prevention can build capacity within a community to take control of its own health.Keywords: rural health education, malaria, informatic
Resting vs. active: a meta-analysis of the intra- and inter-specific associations between minimum, sustained, and maximum metabolic rates in vertebrates
Variation in aerobic capacity has far reaching consequences for the physiology, ecology, and evolution of vertebrates. Whether at rest or active, animals are constrained to operate within the energetic bounds determined by their minimum (minMR) and sustained or maximum metabolic rates (upperMR). MinMR and upperMR can differ considerably among individuals and species but are often presumed to be mechanistically linked to one another. Specifically, minMR is thought to reflect the idling cost of the machinery needed to support upperMR. However, previous analyses based on limited datasets have come to conflicting conclusions regarding the generality and strength of their association.
Here we conduct the first comprehensive assessment of their relationship, based on a large number of published estimates of both the intra-specific (n = 176) and inter-specific (n = 41) phenotypic correlations between minMR and upperMR, estimated as either exercise-induced maximum metabolic rate (VO2max), cold-induced summit metabolic rate (Msum), or daily energy expenditure (DEE).
Our meta-analysis shows that there is a general positive association between minMR and upperMR that is shared among vertebrate taxonomic classes. However, there was stronger evidence for intra-specific correlations between minMR and Msum and between minMR and DEE than there was for a correlation between minMR and VO2max across different taxa. As expected, inter-specific correlation estimates were consistently higher than intra-specific estimates across all traits and vertebrate classes.
An interesting exception to this general trend was observed in mammals, which contrast with birds and exhibit no correlation between minMR and Msum. We speculate that this is due to the evolution and recruitment of brown fat as a thermogenic tissue, which illustrates how some species and lineages might circumvent this seemingly general association.
We conclude that, in spite of some variability across taxa and traits, the contention that minMR and upperMR are positively correlated generally holds true both within and across vertebrate species. Ecological and comparative studies should therefore take into consideration the possibility that variation in any one of these traits might partly reflect correlated responses to selection on other metabolic parameters
The effect of attractions on the local structure of liquids and colloidal fluids
We revisit the role of attractions in liquids and apply these concepts to
colloidal suspensions. Two means are used to investigate the structure; the
pair correlation function and a recently developed topological method. The
latter identifies structures topologically equivalent to ground state clusters
formed by isolated groups of 5 < m < 13 particles, which are specific to the
system under consideration. Our topological methodology shows that, in the case
of Lennard-Jones, the addition of attractions increases the system's ability to
form larger (m>8) clusters, although pair-correlation functions are almost
identical. Conversely, in the case of short-ranged attractions, pair
correlation functions show a significant response to adding attraction, while
the liquid structure exhibits a strong decrease in clustering upon adding
attractions. Finally, a compressed, weakly interacting system shows a similar
pair structure and topology.Comment: 22 page
Temperature as an external field for colloid-polymer mixtures : "quenching" by heating and "melting" by cooling
We investigate the response to temperature of a well-known colloid-polymer
mixture. At room temperature, the critical value of the second virial
coefficient of the effective interaction for the Asakura-Oosawa model predicts
the onset of gelation with remarkable accuracy. Upon cooling the system, the
effective attractions between colloids induced by polymer depletion are
reduced, because the polymer radius of gyration is decreases as the
theta-temperature is approached. Paradoxically, this raises the effective
temperature, leading to "melting" of colloidal gels. We find the Asakura-Oosawa
model of effective colloid interactions with a simple description of the
polymer temperature response provides a quantitative description of the
fluid-gel transition. Further we present evidence for enhancement of
crystallisation rates near the metastable critical point.Comment: 13 page
Single-photon electroluminescence for on-chip quantum networks
An electrically driven single-photon source has been monolithically integrated with nano-photonic circuitry. Electroluminescent emission from a single InAs/GaAs quantum dot (QD) is channelled through a suspended nanobeam waveguide. The emission line has a linewidth of below 6 μeV, demonstrating the ability to have a high coherence, electrically driven, waveguide coupled QD source. The single-photon nature of the emission is verified by g(2) (τ) correlation measurements. Moreover, in a cross-correlation experiment, with emission collected from the two ends of the waveguide, the emission and propagation of single photons from the same QD is confirmed. This work provides the basis for the development of electrically driven on-chip single-photon sources, which can be readily coupled to waveguide filters, directional couplers, phase shifters, and other elements of quantum photonic networks
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